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GP of Mexico Mexico City 23-10-1966, 65 laps of 5 km, Total distance 325 km
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| Pos | No | Driver | Team-engine | Diff | Reason |
| 1 | - | John Surtees | Cooper-Maserati | 2:06:35.40 | - |
| 2 | - | Jack Brabham | Brabham-Repco | -00:07.82 | - |
| 3 | - | Denny Hulme | Brabham-Repco | -1 lap | - |
| 4 | - | Richie Ginther | Honda | -1 lap | - |
| 5 | - | Dan Gurney | Eagle-Climax | -1 lap | - |
| 6 | - | Jo Bonnier | Cooper-Maserati | -2 laps | - |
| 7 | - | Peter Arundell | Lotus-B.R.M. | -4 laps | - |
| 8 | - | Ronnie Bucknum | Honda | -5 laps | - |
| 9 | - | Pedro Rodriguez | Lotus-Climax | 49 laps | Wheel |
| 10 | - | Bruce McLaren | McLaren-Ford | 40 laps | Engine |
| 11 | - | Jo Siffert | Cooper-Maserati | 33 laps | Suspension |
| 12 | - | Jochen Rindt | Cooper-Maserati | 32 laps | Suspension |
| 13 | - | Innes Ireland | B.R.M. | 28 laps | Transmission |
| 14 | 12 | Jackie Stewart | B.R.M. | 26 laps | Oil leak |
| 15 | - | Bob Bondurant | Eagle-Weslake | 24 laps | Fuel |
| 16 | 11 | Graham Hill | B.R.M. | 18 laps | Engine |
| 17 | - | Moises Solana | Cooper-Maserati | 9 laps | Overheating |
| 18 | 4 | Jim Clark | Lotus-B.R.M. | 9 laps | Gearbox |
| 19 | - | Mike Spence | Lotus-B.R.M. | DNS | - |
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